Rate of reaction, order and molecularity, integrated rate equations, Arrhenius equation, collision theory.
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Q1 · Chemical Kinetics · EASY
For a first-order reaction, the rate constant k = 0.0693 min⁻¹. What is the half-life of this reaction?
Q2 · Chemical Kinetics · MEDIUM
The rate of a reaction quadruples when the temperature changes from 300 K to 310 K. Calculate the activation energy (Ea) for this reaction. (Given: R = 8.314 J mol⁻¹ K⁻¹, log 4 = 0.602)
Q3 · Chemical Kinetics · MEDIUM
A reaction has the rate law: Rate = k[A]²[B]. If the concentration of A is doubled and concentration of B is halved, what will be the effect on the rate of reaction?
Q4 · Chemical Kinetics · HARD
For the decomposition of N₂O₅ in CCl₄ at 318 K: 2N₂O₅ → 4NO₂ + O₂, the concentration of N₂O₅ decreases from 1.00 mol L⁻¹ to 0.25 mol L⁻¹ in 2 hours. If the reaction follows first-order kinetics, what is the rate constant?
Q5 · Chemical Kinetics · EASY
For a first-order reaction, the time required for 75% completion is related to the half-life (t₁/₂) by: